Synthesis of a phosphine imide bearing a hydrosilane moiety, and its water-driven reduction to a phosphine.
نویسندگان
چکیده
Organosilanes bearing a phosphine imide moiety were synthesized and crystallographically characterized. Reaction of the pentacoordinated hydrodiphenylsilyl derivative with water gave [2-(diphenylphosphino)phenyl]diphenylsilanol accompanied by both reduction of the phosphine imide moiety and hydrolytic oxidation of the Si-H moiety.
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ورودعنوان ژورنال:
- Chemical communications
دوره 49 88 شماره
صفحات -
تاریخ انتشار 2013